Forensic Chemistry - Taking a Closer Look at the Evidence of a Crime Scene

After CSI technicians have recovered suspicioussubstance and compare it to another.
material evidence like a possible accelerant at a crimeThe mass spectroscope is a machine that showers a
scene suspected as arson, they bring it back to thecompound with a beam of high-energy electrons that
crime lab and look at the evidence more closely. Thecause the separation of that compound. The resulting
scientific procedures used in an actual crime lab areindividual fragments then pass through an electric or
similar to those you see on the CSI TV shows. Inmagnetic field that separates them according to their
this article, we will discuss some of the proceduresindividual masses. The pattern of fragmentation of
used when CSI technicians examine evidence inthe unknown compound is then compared via
closer detail.computer to known patterns of fragmentation on
In a scientific crime lab, the following procedures arerecord and scrutinized by a technician with the hope
used to analyze compounds up close:of determining a consistency that unveils the
- Gas chromatographycomposition of the unknown compound.
- Mass spectroscopy, andThe GC and MS can be used together. This
- Infrared spectrophotometryconglomerate is called a gas chromatograph-mass
No doubt, you may have heard of thesespectrometer. The GC feeds each separated
terminologies when watching your favorite CSIgaseous substance into the MS which in turn
program.determines the substance's mass spectrum. Just
Gas chromatography (GC) is a method used toabout any substance can be identified using this
identify what a compound is and how far each partcombination.
of it moves through an inert gas, or noble gas. GCFinally, infrared spectrophotometry (IR) is a technique
very quickly separates mixtures of compounds intoused to identify the absorption spectrum of a
individual parts in this way.compound since each compound has a unique infrared
The way GC is performed is that a lab technicianabsorption spectrum. This method determines the
injects a liquid sample into one end of the columnamount of infrared light absorbed by the compound
that is heated and vaporized. The vapor enters theof interest and results in a chemical fingerprint of that
column and flows with the moving inert gas until itsame compound.
reaches another gadget called a detector. DifferentIR can also be used in conjunction with GC, and the
compounds move at different speeds and thusGC-IR combination very quickly gives results that are
separate from each other. During this change, thejust as accurate as the ones given by the GC-MS
individual compounds arrive at the detector atcombination.
different times. It is a scientific marathon for individualInterpreting the Results
compounds. The detector then signals anotherEven though technicians can not always determine
gadget called a recorder that prints a graph, called athe exact manufacturer of a given compound, a
chromatograph, that denotes each of thecomparative analysis between the unknown
compounds detected. Many times, the result of thecompound and those taken from suspected areas
GC are needed by technicians to determine themay help them trace the unknown sample to a
composition of the unknown substance. If they needparticular gas station or hardware store that sells the
more information, technicians can combine the resultsaccelerant.
of the GC with the results of either infraredThough this particular investigative technique is not
spectrophotometry or mass spectroscopy.totally reliable, the investigative criminal scientist may
Mass spectroscopy (MS) is another technique used inbe able to say that it came from a particular source.
a crime lab to determine a substance's chemicalThe next time you watch any of the CSI shows,
makeup. Since no two substances have the exactyou will have better knowledge of what some of
same chemical makeup, or chemical fingerprint, thisthese techniques are used for whenever you hear
gadget can be used to determine the makeup of onethe terminologies we have discussed.