Forensic Chemistry - Using Laboratory Chemicals to Reveal Fingerprints

You have seen it on your favorite CSI TV programclose proximity of the latent prints, allowing the
when the police scientist uses gaseous fumes totechnician to fix and dye the fingerprint
expose fingerprints found at a crime scene. Have yousimultaneously.
ever wondered what those fumes are? Have youSilver nitrate is a chemical ingredient found in
ever heard of terms like "Super Glue" mentioned byblack-and-white photographic film. When CSI
the characters on CSI?technicians apply silver nitrate to a latent fingerprint,
In this article, I will discuss the various kinds ofthe chloride found in fingerprint residue interacts with
laboratory chemicals that are used to reveal invisiblethe silver nitrate and forms another compound called
fingerprints.silver chloride. This new compound reveals a black or
In many crime labs, there are four kinds of chemicalreddish-brown fingerprint in the presence of
reagents used to expose invisible, or latent,ultraviolet light.
fingerprints. They are cyanoacrylate, silver nitrate,The third chemical used to reveal latent fingerprints is
iodine, and ninhydrin.called iodine. When heated up, crystalline iodine
What is cyanoacrylate? Perhaps you know this itemreleases iodine fumes into a fuming chamber, where
by its trade name, Super Glue. It is this same Superthe iodine interacts with the oils found in the latent
Glue that you can purchase at any Home Depot orprint thus producing a brownish colored fingerprint.
Walmart. Cyanoacrylate is the active ingredient thatUnfortunately, this kind of print has a tendency to
makes up 98% of Super Glue. This item has becomefade rather quickly. Therefore, it must be captured
a very practical and innovative forensic tool. Whenon film right away or fixed by spraying it with a
cyanoacrylate is heated or mixed with sodium"fixing solution" made of water and starch. This fixing
hydroxide (NaOH), it releases fumes that interactsolution allows the print to last for weeks or even
with the amino acids that are found in the fingerprintmonths in lieu of a few minutes.
residues found on an object, thus making a whiteThe fourth kind of chemical reagent used to reveal
print.latent fingerprints is ninhydrin. Ninhydrin, also known
After exposure to cyanoacrylate, the fingerprints canas triketohydrindene hydrate, has been used for
then be captured on film as is or treated with amany years by CSI technicians to reveal latent
fluorescent pigment that sticks to the fingerprint. Thefingerprints. An object suspected of containing latent
fingerprint then fluoresces, or glows, under a laser orfingerprints is sprayed with a solution of ninhydrin. It
ultraviolet light source.may take several hours for the fingerprints to show
An object that is suspected to have latentup due to the fact that ninhydrin reacts very slowly
fingerprints in this method many times is exposed towith the oils found in the fingerprint. However,
the fumes inside a gadget called a fuming chamber.heating up the object to a temperature of 80 to 100
The end result is that the fumed fingerprints are nowdegrees Fahrenheit can reduce the reaction time. The
hard and stable as one would expect from Superresulting fingerprint will be a purple/blue print.
Glue. In place of setting up a fuming chamber at theHopefully, you have been educated on the kinds of
scene of a crime, CSI technicians often times use achemicals used on your favorite CSI show. The next
hand held wand-shaped tool that heats up a smalltime you hear any of these chemical tools used on
cartridge of cyanoacrylate mixed together withTV, you will know exactly what they are talking
fluorescent pigment. This tool then releases gases inabout.